Linking the Climate and Thermal Phase Curve of SuperEarth 55 Cancri e

Linking the Climate and Thermal Phase Curve of 55 Cancri e

Authors:

Hammond et al

Abstract: 

The thermal phase curve of 55 Cancri e is the first measurement of the temperature distribution of a tidally locked super-Earth, but raises a number of puzzling questions about the planet's climate. The phase curve has a high amplitude and peak offset, suggesting that it has a significant eastward hot-spot shift as well as a large day–night temperature contrast. We use a general circulation model to model potential climates, and investigate the relation between bulk atmospheric composition and the magnitude of these seemingly contradictory features. We confirm theoretical models of tidally locked circulation are consistent with our numerical model of 55 Cnc e, and rule out certain atmospheric compositions based on their thermodynamic properties. Our best-fitting atmosphere has a significant hot-spot shift and day–night contrast, although these are not as large as the observed phase curve. We discuss possible physical processes that could explain the observations, and show that night-side cloud formation from species such as SiO from a day-side magma ocean could potentially increase the phase curve amplitude and explain the observations. We conclude that the observations could be explained by an optically thick atmosphere with a low mean molecular weight, a surface pressure of several bars, and a strong eastward circulation, with night-side cloud formation a possible explanation for the difference between our model and the observations.

A Case for an Atmosphere on Super-Earth 55 Cancri e

A Case for an Atmosphere on Super-Earth 55 Cancri e

Authors:

Angelo et al

Abstract:

One of the primary questions when characterizing Earth-sized and super-Earth-sized exoplanets is whether they have a substantial atmosphere like Earth and Venus or a bare-rock surface like Mercury. Phase curves of the planets in thermal emission provide clues to this question, because a substantial atmosphere would transport heat more efficiently than a bare-rock surface. Analyzing phase curve photometric data around secondary eclipse has previously been used to study energy transport in the atmospheres of hot Jupiters. Here we use phase curve, Spitzer time-series photometry to study the thermal emission properties of the super-Earth exoplanet 55 Cancri e. We utilize a semi-analytical framework to fit a physical model to the infrared photometric data at 4.5 micron. The model uses parameters of planetary properties including Bond albedo, heat redistribution efficiency (i.e., ratio between radiative timescale and advective timescale of the atmosphere), and atmospheric greenhouse factor. The phase curve of 55 Cancri e is dominated by thermal emission with an eastward-shifted hot spot. We determine the heat redistribution efficiency to be ~1.47, which implies that the advective timescale is on the same order as the radiative timescale. This requirement cannot be met by the bare-rock planet scenario because heat transport by currents of molten lava would be too slow. The phase curve thus favors the scenario with a substantial atmosphere. Our constraints on the heat redistribution efficiency translate to an atmospheric pressure of ~1.4 bar. The Spitzer 4.5-micron band is thus a window into the deep atmosphere of the planet 55 Cancri e.

Cloud formation in metal-rich atmospheres of hot super-Earths like 55 Cnc e and CoRot7b

Cloud formation in metal-rich atmospheres of hot super-Earths like 55 Cnc e and CoRot7b

Authors:

Mahapatra et al

Abstract:

Clouds form in the atmospheres of planets where they can determine the observable spectra, the albedo and phase curves. Cloud properties are determined by the local thermodynamical and chemical conditions of an atmospheric gas. A retrieval of gas abundances requires a comprehension of the cloud formation mechanisms under varying chemical conditions. With the aim of studying cloud formation in metal rich atmospheres, we explore the possibility of clouds in evaporating exoplanets like CoRoT-7b and 55 Cnc e in comparison to a generic set of solar abundances and the metal-rich gas giant HD149026b. We assess the impact of metal-rich, non-solar element abundances on the gas-phase chemistry, and apply our kinetic, non-equilibrium cloud formation model to study cloud structures and their details. We provide an overview of global cloud properties in terms of material compositions, maximum particle formation rates, and average cloud particle sizes for various sets of rocky element abundances. Our results suggest that the conditions on 55 Cnc e and HD149026b should allow the formation of mineral clouds in their atmosphere. The high temperatures on some hot-rocky super-Earths (e.g. the day-side of Corot-7b) result in an ionised atmospheric gas and they prevent gas condensation, making cloud formation unlikely on its day-side.

Water in SuperEarth 55 Cancri e's Atmosphere

A Search for Water in a Super-Earth Atmosphere: High-resolution Optical Spectroscopy of 55Cancri e 

Authors: 

Esteves et al

Abstract:

We present the analysis of high-resolution optical spectra of four transits of 55Cnc e, a low-density super-Earth that orbits a nearby Sun-like star in under 18 hr. The inferred bulk density of the planet implies a substantial envelope, which, according to mass–radius relationships, could be either a low-mass extended or a high-mass compact atmosphere. Our observations investigate the latter scenario, with water as the dominant species. We take advantage of the Doppler cross-correlation technique, high-spectral resolution, and the large wavelength coverage of our observations to search for the signature of thousands of optical water absorption lines. Using our observations with HDS on the Subaru telescope and ESPaDOnS on the Canada–France–Hawaii Telescope, we are able to place a 3σ lower limit of 10 g mol−1 on the mean-molecular weight of 55Cnc e's water-rich (volume mixing ratio >10%), optically thin atmosphere, which corresponds to an atmospheric scale-height of ~80 km. Our study marks the first high-spectral resolution search for water in a super-Earth atmosphere, and demonstrates that it is possible to recover known water-vapor absorption signals in a nearby super-Earth atmosphere, using high-resolution transit spectroscopy with current ground-based instruments.

Can Sodium & Calcium be Detected on 55 Cancri e?

Search for an exosphere in sodium and calcium in the transmission spectrum of exoplanet 55 Cancri e

Authors:

Ridden-Harper et al

Abstract:

The aim of this work is to search for an absorption signal from exospheric sodium (Na) and singly ionized calcium (Ca+) in the optical transmission spectrum of the hot rocky super-Earth 55 Cancri e. Although current best-fitting models to the planet mass and radius require a possible atmospheric component, uncertainties in the radius exist, making it possible that 55 Cnc e could be a hot rocky planet without an atmosphere. High resolution (R∼110000) time-series spectra were analysed of five transits of 55 Cancri e, obtained with three different telescopes (UVES/VLT, HARPS/ESO 3.6m & HARPS-N/TNG). Targeting the sodium D lines and the calcium H and K lines the potential planet exospheric signal was filtered out from the much stronger stellar and telluric signals, making use of the change of the radial component of the orbital velocity of the planet over the transit from -57 to +57 km/sec. Combining all five transit data sets we detect a signal potentially associated with sodium in the planet exosphere at a statistical significance level of 3σ. Combining the four HARPS transits that cover the calcium H and K lines, we also find a potential signal from ionized calcium (4.1σ). Interestingly, this latter signal originates from just one of the transit measurements - with a 4.9σ detection at this epoch. Unfortunately, due to the low significance of the measured sodium signal and the potentially variable Ca+ signal, we estimate the p-values of these signals to be too high (corresponding to

Determing the Volatile Content of SuperEarth 55 Cancri e

Constraining the volatile fraction of planets from transit observations

Author:

Alibert

Abstract:

The determination of the abundance of volatiles in extrasolar planets is very important as it can provide constraints on transport in protoplanetary disks and on the formation location of planets. However, constraining the internal structure of low-mass planets from transit measurements is known to be a degenerate problem. Using planetary structure and evolution models, we show how observations of transiting planets can be used to constrain their internal composition, in particular the amount of volatiles in the planetary interior, and consequently the amount of gas (defined in this paper to be only H and He) that the planet harbors. We show for low-mass gas-poor planets that are located close to their central star that assuming evaporation has efficiently removed the entire gas envelope, it is possible to constrain the volatile fraction of close-in transiting planets. We illustrate this method on the example of 55 Cnc e and show that under the assumption of the absence of gas, the measured mass and radius imply at least 20 % of volatiles in the interior. For planets at larger distances, we show that the observation of transiting planets at different evolutionary ages can be used to set statistical constraints on the volatile content of planets. These results can be used in the context of future missions like PLATO to better understand the internal composition of planets.

SuperEarth 55 Cancri e Probably has no Atmosphere and

A map of the large day–night temperature gradient of a super-Earth exoplanet

Authors:

Demory et al

Abstract:

Over the past decade, observations of giant exoplanets (Jupiter-size) have provided key insights into their atmospheres, but the properties of lower-mass exoplanets (sub-Neptune) remain largely unconstrained because of the challenges of observing small planets. Numerous efforts to observe the spectra of super-Earths—exoplanets with masses of one to ten times that of Earth—have so far revealed only featureless spectra. Here we report a longitudinal thermal brightness map of the nearby transiting super-Earth 55 Cancri e revealing highly asymmetric dayside thermal emission and a strong day–night temperature contrast. Dedicated space-based monitoring of the planet in the infrared revealed a modulation of the thermal flux as 55 Cancri e revolves around its star in a tidally locked configuration. These observations reveal a hot spot that is located 41 ± 12 degrees east of the substellar point (the point at which incident light from the star is perpendicular to the surface of the planet). From the orbital phase curve, we also constrain the nightside brightness temperature of the planet to 1,380 ± 400 kelvin and the temperature of the warmest hemisphere (centred on the hot spot) to be about 1,300 kelvin hotter (2,700 ± 270 kelvin) at a wavelength of 4.5 micrometres, which indicates inefficient heat redistribution from the dayside to the nightside. Our observations are consistent with either an optically thick atmosphere with heat recirculation confined to the planetary dayside, or a planet devoid of atmosphere with low-viscosity magma flows at the surface

SuperEarth 55 Cancri e is Probably a Lava World

An international team of astronomers, led by the University of Cambridge, has obtained the most detailed 'fingerprint' of a rocky planet outside our solar system to date, and found a planet of two halves: one that is almost completely molten, and the other which is almost completely solid.

According to the researchers, conditions on the hot side of the planet are so extreme that it may have caused the atmosphere to evaporate, with the result that conditions on the two sides of the planet vary widely: temperatures on the hot side can reach 2500 degrees Celsius, while temperatures on the cool side are around 1100 degrees. The results are reported in the journal Nature.

Using data from NASA's Spitzer Space Telescope, the researchers examined a planet known as 55 Cancri e, which orbits a sun-like star located 40 light years away in the Cancer constellation, and have mapped how conditions on the planet change throughout a complete orbit, the first time this has been accomplished for such a small planet.

55 Cancri e is a 'super Earth': a rocky exoplanet about twice the size and eight times the mass of Earth, and orbits its parent star so closely that a year lasts just 18 hours. The planet is also tidally locked, meaning that it always shows the same face to its parent star, similar to the Moon, so there is a permanent 'day' side and a 'night' side. Since it is among the nearest super Earths whose composition can be studied, 55 Cancri e is among the best candidates for detailed observations of surface and atmospheric conditions on rocky exoplanets.

link.

55 Cancri e's Atmosphere Contains Prussic Acid, Hydrogen, Helium & LOTS of Carbon

For the first time astronomers were able to analyse the atmosphere of an exoplanet in the class known as super-Earths. Using data gathered with the NASA/ESA Hubble Space Telescope and new analysis techniques, the exoplanet 55 Cancri e is revealed to have a dry atmosphere without any indications of water vapour. The results, to be published in the Astrophysical Journal, indicate that the atmosphere consists mainly of hydrogen and helium.

The international team, led by scientists from University College London (UCL) in the UK, took observations of the nearby exoplanet 55 Cancri e, a super-Earth with a mass of eight Earth-masses [1]. It is located in the planetary system of 55 Cancri, a star about 40 light-years from Earth.

Using observations made with the Wide Field Camera 3 (WFC3) on board the NASA/ESA Hubble Space Telescope, the scientists were able to analyse the atmosphere of this exoplanet. This makes it the first detection of gases in the atmosphere of a super-Earth. The results allowed the team to examine the atmosphere of 55 Cancri e in detail and revealed the presence of hydrogen and helium, but no water vapour. These results were only made possible by exploiting a newly-developed processing technique.

"This is a very exciting result because it's the first time that we have been able to find the spectral fingerprints that show the gases present in the atmosphere of a super-Earth," explains Angelos Tsiaras, a PhD student at UCL, who developed the analysis technique along with his colleagues Ingo Waldmann and Marco Rocchetto. "The observations of 55 Cancri e's atmosphere suggest that the planet has managed to cling on to a significant amount of hydrogen and helium from the nebula from which it originally formed."

Super-Earths like 55 Cancri e are thought to be the most common type of planet in our galaxy. They acquired the name 'super-Earth' because they have a mass larger than that of the Earth but are still much smaller than the gas giants in the Solar System. The WFC3 instrument on Hubble has already been used to probe the atmospheres of two other super-Earths, but no spectral features were found in those previous studies [2].

55 Cancri e, however, is an unusual super-Earth as it orbits very close to its parent star. A year on the exoplanet lasts for only 18 hours and temperatures on the surface are thought to reach around 2000 degrees Celsius. Because the exoplanet is orbiting its bright parent star at such a small distance, the team was able to use new analysis techniques to extract information about the planet, during its transits in front of the host star.

Observations were made by scanning the WFC3 very quickly across the star to create a number of spectra. By combining these observations and processing them through analytic software, the researchers were able to retrieve the spectrum of 55 Cancri e embedded in the light of its parent star.

"This result gives a first insight into the atmosphere of a super-Earth. We now have clues as to what the planet is currently like and how it might have formed and evolved, and this has important implications for 55 Cancri e and other super-Earths," said Giovanna Tinetti, also from UCL, UK.

Intriguingly, the data also contain hints of the presence of hydrogen cyanide, a marker for carbon-rich atmospheres.

"Such an amount of hydrogen cyanide would indicate an atmosphere with a very high ratio of carbon to oxygen," said Olivia Venot, KU Leuven, who developed an atmospheric chemical model of 55 Cancri e that supported the analysis of the observations.

link.

paper originally posted here on Dec 1st.

SuperEarth 55 Cancri e's Atmosphere is Carbon and Hydrogen Rich, may Have Hydrogen cyanide

Detection of an atmosphere around the super-Earth 55 Cancri e

Authors:

Tsiaras et al

Abstract:

Before the discovery of extrasolar planets, super-Earths belonged in the realm of science fiction. However, they appear to constitute the most common planetary type in our galaxy. We know very little about these planets beyond very basic planetary and orbital parameters. The WFC3 camera onboard the HST has enabled the spectroscopic observations of the atmospheres of two super-Earths, GJ1214b and HD97658b, with unprecedented precision; but the published spectra of these two objects are featureless, suggesting an atmosphere covered by thick clouds or made of molecular species much heavier than hydrogen. We report here the analysis of the observations performed with the WFC3 of a third, very hot, super-Earth, 55 Cancri e. Given the brightness of 55 Cancri, the observations were obtained in scanning mode, adopting a very long scanning length and a very high scanning speed. These observational parameters are coupled with the geometrical distortions of the instrument, so we have developed a specialized pipeline to de-correlate the signal from the systematics. We measure the transit depth per wavelength channel with an average relative uncertainty of 21 ppm and find a spectral modulation of about 100 ppm. These results suggest that 55 Cancri e is surrounded by an atmosphere, which is hydrogen-rich. Our fully Bayesian spectral retrieval code, TauREx, has identified HCN to be one of the possible trace gases in the atmosphere. While additional observations in a broader wavelength range will be needed to confirm the HCN detection, we discuss here the implications of such result. We adopt a chemical scheme developed with combustion specialists and validated by a wide range of experiments. Our chemical model indicates that a relatively high mixing ratio of HCN would reveal a high C/O ratio, suggesting the atmosphere of 55 Cancri e is a carbon-rich environment.

SuperEarth rho 55 Cancri e may Have had a VERY Dramatic History (not counting the volcanoes)

On the potentially dramatic history of the super-Earth rho 55 Cancri e

Authors:

Hansen et al

Abstract:

We demonstrate that tidal evolution of the inner planet (`e') of the system orbiting the star rho 55 Cancri could have led to passage through two secular resonances with other planets in the system. The consequence of this evolution is excitation of both the planetary eccentricity and inclination relative to the original orbital plane. The large mass ratio between the innermost planet and the others means that these excitations can be of substantial amplitude and can have dramatic consequences for the system organisation. Such evolution can potentially explain the large observed mutual inclination between the innermost and outermost planets in the system, and implies that tidal heating could have substantially modified the structure of planet e, and possibly reduced its mass by Roche lobe overflow. Similar inner secular resonances may be found in many multiple planet systems and suggest that many of the innermost planets in these systems could have suffered similar evolutions.

Has the First Extrasolar Volcanic Activity Been Detected on SuperEarth 55 Canceri e? Or an ExoMoon?

Variability in the super-Earth 55 Cnc e

Authors:

Demory et al

Abstract:

Considerable progress has been made in recent years in observations of atmospheric signatures of giant exoplanets, but processes in rocky exoplanets remain largely unknown due to major challenges in observing small planets. Numerous efforts to observe spectra of super-Earths, exoplanets with masses of 1-10 Earth masses, have thus far revealed only featureless spectra. In this paper we report a 4-σ detection of variability in the dayside thermal emission from the transiting super-Earth 55 Cancri e. Dedicated space-based monitoring of the planet in the mid-infrared over eight eclipses revealed the thermal emission from its dayside atmosphere varying by a factor 3.7 between 2012 and 2013. The amplitude and trend of the variability are not explained by potential influence of star spots or by local thermal or compositional changes in the atmosphere over the short span of the observations. The possibility of large scale surface activity due to strong tidal interactions possibly similar to Io, or the presence of circumstellar/circumplanetary material appear plausible and motivate future long-term monitoring of the planet.

Ground Based Telescope Successfully Detects SuperEarth 55 Cnc e

Ground-Based Transit Observations of the Super-Earth 55 Cnc e

Authors:

de Mooij et al

Abstract:

We report the first ground-based detections of the shallow transit of the super-Earth exoplanet 55 Cnc e using a 2-meter-class telescope. Using differential spectrophotometry, we observed one transit in 2013 and another in 2014, with average spectral resolutions of ~700 and ~250, spanning the Johnson BVR photometric bands. We find a white-light planet-to-star radius ratio of 0.0190 -0.0027+0.0023 from the 2013 observations and 0.0200 -0.0018+0.0017 from the 2014 observations. The two datasets combined results in a radius ratio of 0.0198 -0.0014+0.0013. These values are all in agreement with previous space-based results. Scintillation noise in the data prevents us from placing strong constraints on the presence of an extended hydrogen-rich atmosphere. Nevertheless, our detections of 55 Cnc e in transit demonstrate that moderate-size telescopes on the ground will be capable of routine follow-up observations of super-Earth candidates discovered by the Transiting Exoplanet Survey Satellite (TESS) around bright stars. We expect it will be also possible to place constraints on the atmospheric characteristics of those planets by devising observational strategies to minimize scintillation noise.

How to Best Characterize Water-rich SuperEarth Atmospheres

Optimal Measures for Characterizing Water-rich Super-Earths

Authors:

Madhusudhan et al

Abstract:

The detection and atmospheric characterization of super-Earths is one of the major frontiers of exoplanetary science. Currently, extensive efforts are underway to detect molecules, particularly H2O, in super-Earth atmospheres. In the present work, we develop a systematic set of strategies to identify and observe potentially H2O-rich super-Earths that provide the best prospects for characterizing their atmospheres using existing instruments. Firstly, we provide analytic prescriptions and discuss factors that need to be taken into account while planning and interpreting observations of super-Earth radii and spectra. We discuss how observations in different spectral bandpasses constrain different atmospheric properties of a super-Earth, including radius and temperature of the planetary surface as well as the mean molecular mass, the chemical composition and thermal profile of the atmosphere. In particular, we caution that radii measured in certain bandpasses can induce biases in the interpretation of the interior compositions. Secondly, we investigate the detectability of H2O-rich super-Earth atmospheres using the HST WFC3 spectrograph as a function of the planetary properties and stellar brightness. We find that highly irradiated super-Earths orbiting bright stars, such as 55 Cancri e, present better candidates for atmospheric characterization compared to cooler planets such as GJ 1214b even if the latter orbit lower-mass stars. Besides being better candidates for both transmission and emission spectroscopy, hotter planets offer higher likelihood of cloud-free atmospheres which aid tremendously in the observation and interpretation of spectra. Finally, we present case studies of two super-Earths, GJ 1214b and 55 Cancri e, using available data and models of their interiors and atmospheres.

Silicon-Carbon Worlds' Internal Structure & 55 Cancri e

INTERIOR PHASE TRANSFORMATIONS AND MASS-RADIUS RELATIONSHIPS OF SILICON-CARBON PLANETS

Authors:

Wilson et al

Abstract:

Planets such as 55 Cancri e orbiting stars with a high carbon-to-oxygen ratio may consist primarily of silicon and carbon, with successive layers of carbon, silicon carbide, and iron. The behavior of silicon-carbon materials at the extreme pressures prevalent in planetary interiors, however, has not yet been sufficiently understood. In this work, we use simulations based on density functional theory to determine high-pressure phase transitions in the silicon-carbon system, including the prediction of new stable compounds with Si2C and SiC2 stoichiometry at high pressures. We compute equations of state for these silicon-carbon compounds as a function of pressure, and hence derive interior structural models and mass-radius relationships for planets composed of silicon and carbon. Notably, we predict a substantially smaller radius for SiC planets than in previous models, and find that mass radius relationships for SiC planets are indistinguishable from those of silicate planets. We also compute a new equation of state for iron. We rederive interior models for 55 Cancri e and are able to place more stringent restrictions on its composition.

New Obervations of 55 Cnc e

Rossiter-McLaughlin Observations of 55 Cnc e

Authors:

Lopez-Morales et al

Abstract:

We present Rossiter-McLaughlin observations of the transiting super-Earth 55 Cnc e collected during six transit events between January 2012 and November 2013 with HARPS and HARPS-N. We detect no radial-velocity signal above 35 cm/s (3-sigma) and confine the stellar v sin i to 0.2 +/- 0.5 km/s. The star appears to be a very slow rotator, producing a very low amplitude Rossiter-McLaughlin effect. Given such a low amplitude, the Rossiter-McLaughlin effect of 55 Cnc e is undetected in our data, and any spin-orbit angle of the system remains possible. We also performed Doppler tomography and reach a similar conclusion. Our results offer a glimpse of the capacity of future instrumentation to study low amplitude Rossiter-McLaughlin effects produced by super-Earths.

SuperEarth 55 Cancri e is in a Polar Orbit Around its Host Star

Detecting the spin-orbit misalignment of the super-Earth 55 Cnc e

Authors:

Bourrier et al

Abstract:

We present time-resolved spectroscopy of transits of the super-Earth 55 Cnc e using HARPS-N observations. We devised an empirical correction for the "color effect" affecting the radial velocity residuals from the Keplerian fit, which significantly improves their dispersion with respect to the HARPS-N pipeline standard data-reduction. Using our correction, we were able to detect the smallest Rossiter-McLaughlin anomaly amplitude of an exoplanet so far (~60 cm/s). The super-Earth 55 Cnc e is also the smallest exoplanet with a Rossiter-McLaughlin anomaly detection. We measured the sky-projected obliquity lambda = 72.4 (+12.7 -11.5 deg), indicating that the planet orbit is prograde, highly misaligned and nearly polar compared to the stellar equator. The entire 55 Cancri system may have been highly tilted by the presence of a stellar companion.

The Chemistry of Exoatmospheres for SuperEarths and Mini Neptunes

PHOTOCHEMISTRY IN TERRESTRIAL EXOPLANET ATMOSPHERES. III. PHOTOCHEMISTRY AND THERMOCHEMISTRY IN THICK ATMOSPHERES ON SUPER EARTHS AND MINI NEPTUNES

Authors:

Hu et al


Abstract:

Some super Earths and mini Neptunes will likely have thick atmospheres that are not H2-dominated. We have developed a photochemistry-thermochemistry kinetic-transport model for exploring the compositions of thick atmospheres on super Earths and mini Neptunes, applicable for both H2-dominated atmospheres and non-H2-dominated atmospheres. Using this model to study thick atmospheres for wide ranges of temperatures and elemental abundances, we classify them into hydrogen-rich atmospheres, water-rich atmospheres, oxygen-rich atmospheres, and hydrocarbon-rich atmospheres. We find that carbon has to be in the form of CO2 rather than CH4 or CO in a H2-depleted water-dominated thick atmosphere and that the preferred loss of light elements from an oxygen-poor carbon-rich atmosphere leads to the formation of unsaturated hydrocarbons (C2H2 and C2H4). We apply our self-consistent atmosphere models to compute spectra and diagnostic features for known transiting low-mass exoplanets GJ 1214 b, HD 97658 b, and 55 Cnc e. For GJ 1214 b, we find that (1) C2H2 features at 1.0 and 1.5 μm in transmission and C2H2 and C2H4 features at 9-14 μm in thermal emission are diagnostic for hydrocarbon-rich atmospheres; (2) a detection of water-vapor features and a confirmation of the nonexistence of methane features would provide sufficient evidence for a water-dominated atmosphere. In general, our simulations show that chemical stability has to be taken into account when interpreting the spectrum of a super Earth/mini Neptune. Water-dominated atmospheres only exist for carbon to oxygen ratios much lower than the solar ratio, suggesting that this kind of atmospheres could be rare.