The distant planet GJ 1132b intrigued astronomers when it was discovered last year. Located just 39 light-years from Earth, it might have an atmosphere despite being baked to a temperature of around 450 degrees Fahrenheit. But would that atmosphere be thick and soupy or thin and wispy? New research suggests the latter is much more likely.
Harvard astronomer Laura Schaefer (Harvard-Smithsonian Center for Astrophysics, or CfA) and her colleagues examined the question of what would happen to GJ 1132b over time if it began with a steamy, water-rich atmosphere.
Orbiting so close to its star, at a distance of just 1.4 million miles, the planet is flooded with ultraviolet or UV light. UV light breaks apart water molecules into hydrogen and oxygen, both of which then can be lost into space. However, since hydrogen is lighter it escapes more readily, while oxygen lingers behind.
"On cooler planets, oxygen could be a sign of alien life and habitability. But on a hot planet like GJ 1132b, it's a sign of the exact opposite - a planet that's being baked and sterilized," said Schaefer.
Identifying Planetary Biosignature Impostors: Spectral Features of CO and O4 Resulting from Abiotic O2/O3 Production
Authors:
Schwieterman et al
Abstract:
O2 and O3 have been long considered the most robust individual biosignature gases in a planetary atmosphere, yet multiple mechanisms that may produce them in the absence of life have been described. However, these abiotic planetary mechanisms modify the environment in potentially identifiable ways. Here we briefly discuss two of the most detectable spectral discriminants for abiotic O2/O3: CO and O4. We produce the first explicit self-consistent simulations of these spectral discriminants as they may be seen by JWST. If JWST-NIRISS and/or NIRSpec observe CO (2.35, 4.6 um) in conjunction with CO2 (1.6, 2.0, 4.3 um) in the transmission spectrum of a terrestrial planet it could indicate robust CO2 photolysis and suggest that a future detection of O2 or O3 might not be biogenic. Strong O4 bands seen in transmission at 1.06 and 1.27 um could be diagnostic of a post-runaway O2-dominated atmosphere from massive H-escape. We find that for these false positive scenarios, CO at 2.35 um, CO2 at 2.0 and 4.3 um, and O4 at 1.27 um are all stronger features in transmission than O2/O3 and could be detected with SNRs ≳ 3 for an Earth-size planet orbiting a nearby M dwarf star with as few as 10 transits, assuming photon-limited noise. O4 bands could also be sought in UV/VIS/NIR reflected light (at 0.345, 0.36, 0.38, 0.445, 0.475, 0.53, 0.57, 0.63, 1.06, and 1.27 um) by a next generation direct-imaging telescope such as LUVOIR/HDST or HabEx and would indicate an oxygen atmosphere too massive to be biologically produced.
Abiotic O2 Levels on Planets around F, G, K, and M Stars: Possible False Positives for Life?
Authors:
Harman et al
Abstract:
In the search for life on Earth-like planets around other stars, the first (and likely only) information will come from the spectroscopic characterization of the planet's atmosphere. Of the countless number of chemical species terrestrial life produces, only a few have the distinct spectral features and the necessary atmospheric abundance to be detectable. The easiest of these species to observe in Earth's atmosphere is O2 (and its photochemical byproduct, O3). But O2 can also be produced abiotically by photolysis of CO2, followed by recombination of O atoms with each other. CO is produced in stoichiometric proportions. Whether O2 and CO can accumulate to appreciable concentrations depends on the ratio of far-UV to near-UV radiation coming from the planet's parent star and on what happens to these gases when they dissolve in a planet's oceans. Using a one-dimensional photochemical model, we demonstrate that O2 derived from CO2 photolysis should not accumulate to measurable concentrations on planets around F- and G-type stars. K-star, and especially M-star planets, however, may build up O2 because of the low near-UV flux from their parent stars, in agreement with some previous studies. On such planets, a 'false positive' for life is possible if recombination of dissolved CO and O2 in the oceans is slow and if other O2 sinks (e.g., reduced volcanic gases or dissolved ferrous iron) are small. O3, on the other hand, could be detectable at UV wavelengths (λ less than 300 nm) for a much broader range of boundary conditions and stellar types.
Titania may produce abiotic oxygen atmospheres on habitable exoplanets
Authors:
Narita et al
Abstract:
The search for habitable exoplanets in the Universe is actively ongoing in the field of astronomy. The biggest future milestone is to determine whether life exists on such habitable exoplanets. In that context, oxygen in the atmosphere has been considered strong evidence for the presence of photosynthetic organisms. In this paper, we show that a previously unconsidered photochemical mechanism by titanium(IV) oxide (titania) can produce abiotic oxygen from liquid water under near ultraviolet (NUV) lights on the surface of exoplanets. Titania works as a photocatalyst to dissociate liquid water in this process. This mechanism offers a different source of a possibility of abiotic oxygen in atmospheres of exoplanets from previously considered photodissociation of water vapor in upper atmospheres by extreme ultraviolet (XUV) light. Our order-of-magnitude estimation shows that possible amounts of oxygen produced by this abiotic mechanism can be comparable with or even more than that in the atmosphere of the current Earth, depending on the amount of active surface area for this mechanism. We conclude that titania may act as a potential source of false signs of life on habitable exoplanets.

The Earth's atmosphere contains oxygen because plants continuously produce it through photosynthesis. This abundant supply of oxygen allows life forms like animals to flourish. Therefore, oxygen had been thought to be an essential biomarker for life on extrasolar planets. But now, a research assistant professor Norio Narita of the Astrobiology Center of National Institutes of Natural Sciences (NINS), which was founded in April 2015, and an associate professor Shigeyuki Masaoka, of the Institute of Molecular Science of NINS, have presented a novel hypothesis that it could be possible for planets to have large quantities of abiotic (non-biologically produced) oxygen. This study is a good example of interdisciplinary studies that combine knowledge from different fields of science to promote astrobiology in the search for life on extrasolar planets. The study is published in Scientific Reports on Sep 10, 2015.
Until now, it had been thought that if a planet has oxygen, that must mean that some form of plants are producing it through photosynthesis. Therefore, it had been assumed that when searching for signs of life on habitable extrasolar planets, the presence of oxygen in the atmosphere could be considered a definitive biomarker. However, non-biological chemical reactions can also affect atmospheric compositions of extrasolar planets. Now, the research team led by Dr. Narita has shown that, abiotic oxygen produced by the photocatalytic reaction of titanium oxide, which is known to be abundant on the surfaces of terrestrial planets, meteorolites, and the Moon in the Solar System, cannot be discounted.
For a planet with an environment similar to the Sun-Earth system, continuous photocatalytic reaction of titanium oxide on about 0.05 % of the planetary surface could produce the amount of oxygen found in the current Earth's atmosphere. In addition, the team estimated the amount of possible oxygen production for habitable planets around other types of host stars with various masses and temperatures. They found that even in the least efficient production case of a low-temperature star, the photocatalytic reaction of the titanium oxide on about 3% of the planetary surface could maintain this level of atmospheric oxygen through abiotic processes. In other words, it is possible that a habitable extrasolar planet could maintain an atmosphere with Earth-like oxygen, even without organisms to perform photosynthesis.
Stabilization of CO2 Atmospheres on Exoplanets around M Dwarf Stars
Authors:
Gao et al
Abstract:
We investigate the chemical stability of CO2-dominated atmospheres of M dwarf terrestrial exoplanets using a 1-dimensional photochemical model. On planets orbiting Sun-like stars, the photolysis of CO2 by Far-UV (FUV) radiation is balanced by the reaction between CO and OH, the rate of which depends on H2O abundance. By comparison, planets orbiting M dwarf stars experience higher FUV radiation compared to planets orbiting Sun-like stars, and they are also likely to have low H2O abundance due to M dwarfs having a prolonged, high-luminosity pre-main sequence (Luger & Barnes 2015). We show that, for H2O-depleted planets around M dwarfs, a CO2-dominated atmosphere is stable to conversion to CO and O2 by relying on a catalytic cycle involving H2O2 photolysis. However, this cycle breaks down for planets with atmospheric hydrogen mixing ratios below ~1 ppm, resulting in ~40% of the atmospheric CO2 being converted to CO and O2 on a time scale of 1 Myr. The increased abundance of O2 also results in high O3 concentrations, which reacts with HO2 to generate OH, forming another catalytic cycle capable of stabilizing CO2. For atmospheres with less htan 0.1 ppm hydrogen, excess O atoms resulting from O3 photolysis react with CO and a third body to directly produce CO2. This series of catalytic cycles places an upper limit of ~50% on the amount of CO2 that can be destroyed via photolysis in such a dry atmosphere, which is enough to generate abundances of abiotic O2 and O3 rivaling that of modern Earth. Discrimination between O2 and O3 produced biologically and those produced abiotically through photolysis can perhaps be accomplished by noting the lack of water features in the spectra of these H2O-depleted planets, which necessitates observations in the infrared.

Extreme Water Loss and Abiotic O2 Buildup On Planets Throughout the Habitable Zones of M Dwarfs
Authors:
Luger et al
Abstract:
We show that terrestrial planets in the habitable zones of M dwarfs older than ∼ 1 Gyr could have been in runaway greenhouses for several hundred Myr following their formation due to the star's extended pre-main sequence phase, provided they form with abundant surface water. Such prolonged runaway greenhouses can lead to planetary evolution divergent from that of Earth. During this early runaway phase, photolysis of water vapor and hydrogen/oxygen escape to space can lead to the loss of several Earth oceans of water from planets throughout the habitable zone, regardless of whether the escape is energy-limited or diffusion-limited. We find that the amount of water lost scales with the planet mass, since the diffusion-limited hydrogen escape flux is proportional to the planet surface gravity. In addition to undergoing potential desiccation, planets with inefficient oxygen sinks at the surface may build up hundreds to thousands of bars of abiotically produced O2, resulting in potential false positives for life. The amount of O2 that builds up also scales with the planet mass; we find that O2 builds up at a constant rate that is controlled by diffusion: ∼ 5 bars/Myr on Earth-mass planets and up to ∼ 25 bars/Myr on super-Earths. As a result, some recently discovered super-Earths in the habitable zone such as GJ 667Cc could have built up as many as 2000 bars of O2 due to the loss of up to 10 Earth oceans of water. The fate of a given planet strongly depends on the extreme ultraviolet flux, the duration of the runaway regime, the initial water content, and the rate at which oxygen is absorbed by the surface. In general, we find that the initial phase of high luminosity may compromise the habitability of many terrestrial planets orbiting low mass stars.