Nitrogen & Oxygen in the Exoplanet Atmosphere is a Biosignature

Modeling pN2 through Geological Time: Implications for Planetary Climates and Atmospheric Biosignatures

Authors:

Stüeken et al

Abstract:

Nitrogen is a major nutrient for all life on Earth and could plausibly play a similar role in extraterrestrial biospheres. The major reservoir of nitrogen at Earth's surface is atmospheric N2, but recent studies have proposed that the size of this reservoir may have fluctuated significantly over the course of Earth's history with particularly low levels in the Neoarchean—presumably as a result of biological activity. We used a biogeochemical box model to test which conditions are necessary to cause large swings in atmospheric N2 pressure. Parameters for our model are constrained by observations of modern Earth and reconstructions of biomass burial and oxidative weathering in deep time. A 1-D climate model was used to model potential effects on atmospheric climate. In a second set of tests, we perturbed our box model to investigate which parameters have the greatest impact on the evolution of atmospheric pN2 and consider possible implications for nitrogen cycling on other planets. Our results suggest that (a) a high rate of biomass burial would have been needed in the Archean to draw down atmospheric pN2 to less than half modern levels, (b) the resulting effect on temperature could probably have been compensated by increasing solar luminosity and a mild increase in pCO2, and (c) atmospheric oxygenation could have initiated a stepwise pN2 rebound through oxidative weathering. In general, life appears to be necessary for significant atmospheric pN2 swings on Earth-like planets. Our results further support the idea that an exoplanetary atmosphere rich in both N2 and O2 is a signature of an oxygen-producing biosphere.

Raman Scattering by Molecular Hydrogen and Nitrogen in Exoplanetary Atmospheres

Raman Scattering by Molecular Hydrogen and Nitrogen in Exoplanetary Atmospheres

Authors:

Oklopčić et al

Abstract:

An important source of opacity in the atmospheres of exoplanets at short visible and near-UV wavelengths is Rayleigh scattering of light on molecules. It is accompanied by a related, albeit weaker process -- Raman scattering. In this paper, we analyze the signatures of Raman scattering imprinted in the reflected light and the geometric albedo of exoplanets, which could provide valuable information about planetary atmospheres. Raman scattering affects the geometric albedo spectra of planets in two main ways. Firstly, it causes filling-in of strong absorption lines in the incident radiation, thus producing sharp peaks in the albedo. Secondly, it shifts the wavelengths of spectral features in the reflected light causing the so-called Raman ghost lines. Observing the Raman peaks in the albedo could be used to measure the column density of the scattering molecule, thus providing constrains on the presence of clouds and hazes in the atmosphere. Observing the Raman ghost lines could be used to spectroscopically identify the main scatterer in the atmosphere -- molecules like H2 or N2 that do not have prominent spectral signatures in the optical wavelength range. If detected, ghost lines could also provide information about the temperature of the atmosphere. In this work we investigate the effects of Raman scattering in hydrogen- and nitrogen-dominated atmospheres. We analyze the feasibility of detecting the signatures of Raman scattering with the existing and future observational facilities, and of using these signatures as probes of exoplanetary atmospheres.

Nitrogen abundances in stars with planets

CNO behaviour in planet-harbouring stars. I Nitrogen abundances in stars with planets

Authors:

Suárez-Andrés et al

Abstract:

Carbon, nitrogen, and oxygen (CNO) are key elements in stellar formation and evolution, and their abundances should also have a significant impact on planetary formation and evolution. We present a detailed spectroscopic analysis of 74 solar-type stars, 42 of which are known to harbour planets. We determine the nitrogen abundances of these stars and investigate a possible connection between N and the presence of planetary companions. We used VLT/UVES to obtain high-resolution near-UV spectra of our targets. Spectral synthesis of the NH band at 3360A was performed with the spectral synthesis codes MOOG and FITTING. We identify several spectral windows from which accurate N abundance can be obtained. Nitrogen distributions for stars with and without planets show that planet hosts are nitrogen-rich when compared to single stars. However, given the linear trend between [N/Fe] vs [Fe/H], this fact can be explained as being due to the metal-rich nature of planet hosts. We conclude that reliable N abundances can be derived for metal-rich solar type stars from the near UV molecular band at 3360A. We confirm a linear trend between [N/Fe] and metallicity expected from standard models of Galactic chemical evolution.

Some Lambda Boo Stars are Eating Their hot Jupiters

Lambda Boo Abundance Patterns: Accretion from Orbiting Sources

Authors:

Jura et al

Abstract:

The abundance anomalies in lambda Boo stars are popularly explained by element-specific mass inflows at rates that are much greater than empirically-inferred bounds for interstellar accretion. Therefore, a lambda Boo star's thin outer envelope must derive from a companion star, planet, analogs to Kuiper Belt Objects or a circumstellar disk. Because radiation pressure on gas-phase ions might selectively allow the accretion of carbon, nitrogen, and oxygen and inhibit the inflow of elements such as iron, the source of the acquired matter need not contain dust. We propose that at least some lambda Boo stars accrete from the winds of hot Jupiters.

Detecting Molecular Nitrogen in Exoplanetary Atmospheres

Detecting and Constraining N2 Abundances in Planetary Atmospheres Using Collisional Pairs

Authors:

Schwiertman et al

Abstract:

Characterizing the bulk atmosphere of a terrestrial planet is important for determining surface pressure and potential habitability. Molecular nitrogen (N2) constitutes the largest fraction of Earth′s atmosphere and is likely to be a major constituent of many terrestrial exoplanet atmospheres. Due to its lack of significant absorption features, N2 is extremely difficult to remotely detect. However, N2 produces an N2-N2 collisional pair, (N2)2, which is spectrally active. Here we report the detection of (N2)2 in Earth′s disk-integrated spectrum. By comparing spectra from NASA′s EPOXI mission to synthetic spectra from the NASA Astrobiology Institute′s Virtual Planetary Laboratory three-dimensional spectral Earth model, we find that (N2)2 absorption produces a ~35% decrease in flux at 4.15 μm. Quantifying N2 could provide a means of determining bulk atmospheric composition for terrestrial exoplanets and could rule out abiotic O2 generation, which is possible in rarefied atmospheres. To explore the potential effects of (N2)2 in exoplanet spectra, we used radiative transfer models to generate synthetic emission and transit transmission spectra of self-consistent N2-CO2-H2O atmospheres, and analytic N2-H2 and N2-H2-CO2 atmospheres. We show that (N2)2 absorption in the wings of the 4.3 μm CO2 band is strongly dependent on N2 partial pressures above 0.5 bar and can significantly widen this band in thick N2 atmospheres. The (N2)2 transit transmission signal is up to 10 ppm for an Earth-size planet with an N2-dominated atmosphere orbiting within the HZ of an M5V star and could be substantially larger for planets with significant H2 mixing ratios.

How the Initial Abundances of Nitrogen Effect a Protoplanetary Disk

The Effects of Initial Abundances on Nitrogen in Protoplanetary Disks

Authors:

Schwarz et al

Abstract:

The dominant form of nitrogen provided to most solar system bodies is currently unknown, though available measurements show that the detected nitrogen in solar system rocks and ices is depleted with respect to solar abundances and the interstellar medium. We use a detailed chemical/physical model of the chemical evolution of a protoplanetary disk to explore the evolution and abundance of nitrogen-bearing molecules. Based on this model we analyze how initial chemical abundances, provided as either gas or ice during the early stages of disk formation, influence which species become the dominant nitrogen bearers at later stages. We find that a disk with the majority of its initial nitrogen in either atomic or molecular nitrogen is later dominated by atomic and molecular nitrogen as well as NH3 and HCN ices, where the dominant species varies with disk radius.

When nitrogen is initially in gaseous ammonia, it later becomes trapped in ammonia ice except in the outer disk where atomic nitrogen dominates. For a disk with the initial nitrogen in the form of ammonia ice the nitrogen remains trapped in the ice as NH3 at later stages. The model in which most of the initial nitrogen is placed in atomic N best matches the ammonia abundances observed in comets. Furthermore the initial state of nitrogen influences the abundance of N2H+, which has been detected in protoplanetary disks. Strong N2H+ emission is found to be indicative of an N2 abundance greater than nN2/nH2>10−6, in addition to tracing the CO snow line. Our models also indicate that NO is potentially detectable, with lower N gas abundances leading to higher NO abundances.