Gas mass tracers in protoplanetary disks: CO is still the best

Gas mass tracers in protoplanetary disks: CO is still the best

Authors:

Molyarova et al

Abstract:
Protoplanetary disk mass is a key parameter controlling the process of planetary system formation. CO molecular emission is often used as a tracer of gas mass in the disk. In this study we consider the ability of CO to trace the gas mass over a wide range of disk structural parameters and search for chemical species that could possibly be used as alternative mass tracers to CO. Specifically, we apply detailed astrochemical modeling to a large set of models of protoplanetary disks around low-mass stars, to select molecules with abundances correlated with the disk mass and being relatively insensitive to other disk properties. We do not consider sophisticated dust evolution models, restricting ourselves with the standard astrochemical assumption of 0.1 μm dust. We find that CO is indeed the best molecular tracer for total gas mass, despite the fact that it is not the main carbon carrier, provided reasonable assumptions about CO abundance in the disk are used. Typically, chemical reprocessing lowers the abundance of CO by a factor of 3, compared to the case of photo-dissociation and freeze-out as the only ways of CO depletion. On average only 13% C-atoms reside in gas-phase CO, albeit with variations from 2 to 30%. CO2, H2O and H2CO can potentially serve as alternative mass tracers, the latter two being only applicable if disk structural parameters are known.

The Effects of Protostellar Disk Turbulence on CO Emission Lines: A Comparison Study of Disks with Constant CO Abundance vs. Chemically Evolving Disks

The Effects of Protostellar Disk Turbulence on CO Emission Lines: A Comparison Study of Disks with Constant CO Abundance vs. Chemically Evolving Disks 

Authors:

Yu et al

Abstract:
Turbulence is the leading candidate for angular momentum transport in protoplanetary disks and therefore influences disk lifetimes and planet formation timescales. However, the turbulent properties of protoplanetary disks are poorly constrained observationally. Simon et al. (2015) suggested that the ratio of the peak line flux to the flux at line center of the CO J=3-2 transition is a reasonable diagnostic of turbulence, while Flaherty et al. (2015) and Flaherty et al. (2017) found turbulent speeds in HD 163296 smaller than what fully-developed MRI would produce based on the Simon et al. (2015) simulation results. Yet Simon et al. (2015) and Flaherty et al. (2015) assumed a constant CO/H2 ratio of 0.0001 in locations where CO is not frozen-out or photodissociated. Yu et al. (2016) found that the CO abundance varies both with distance from the star and as a function of time because CO molecules are gradually dissociated, with the liberated carbon forming complex organic molecules that freeze out on grain surfaces. We simulate the emission lines of CO based on chemical evolution models presented in Yu et al. (2016), and find that the peak-to-trough ratio changes as a function of time as CO is destroyed. Specifically, a CO-depleted disk with high turbulent velocity mimics the peak-to-trough ratios of a non-CO-depleted disk with lower turbulent velocity. We suggest that disk observers and modelers take into account the possibility of CO depletion when using line peak-to-trough ratios to constrain the degree of turbulence in disks. Assuming that CO/H2 = 0.0001 at all disk radii can lead to underestimates of turbulent speeds in the disk by at least 0.2 km/s.

An ALMA Survey of CO isotopologue emission from Protoplanetary Disks in Chamaeleon I

An ALMA Survey of CO isotopologue emission from Protoplanetary Disks in Chamaeleon I

Authors:

Long et al

Abstract:

The mass of a protoplanetary disk limits the formation and future growth of any planet. Masses of protoplanetary disks are usually calculated from measurements of the dust continuum emission by assuming an interstellar gas-to-dust ratio. To investigate the utility of CO as an alternate probe of disk mass, we use ALMA to survey 13CO and C18O J = 3−2 line emission from a sample of 93 protoplanetary disks around stars and brown dwarfs with masses from 0.03 -- 2 M⊙ in the nearby Chamaeleon I star-forming region. We detect 13CO emission from 17 sources and C18O from only one source. Gas masses for disks are then estimated by comparing the CO line luminosities to results from published disk models that include CO freeze-out and isotope-selective photodissociation. Under the assumption of a typical ISM CO-to-H2 ratios of 10−4, the resulting gas masses are implausibly low, with an average gas mass of ∼ 0.05 MJup as inferred from the average flux of stacked 13CO lines. The low gas masses and gas-to-dust ratios for Cha I disks are both consistent with similar results from disks in the Lupus star-forming region. The faint CO line emission may instead be explained if disks have much higher gas masses, but freeze-out of CO or complex C-bearing molecules is underestimated in disk models. The conversion of CO flux to CO gas mass also suffers from uncertainties in disk structures, which could affect gas temperatures. CO emission lines will only be a good tracer of the disk mass when models for C and CO depletion are confirmed to be accurate.

Disk Masses around Solar-mass Stars are Underestimated by CO Observations

Disk Masses around Solar-mass Stars are Underestimated by CO Observations

Authors:

Yu et al

Abstract:

Gas in protostellar disks provides the raw material for giant planet formation and controls the dynamics of the planetesimal-building dust grains. Accurate gas mass measurements help map the observed properties of planet-forming disks onto the formation environments of known exoplanets. Rare isotopologues of carbon monoxide (CO) have been used as gas mass tracers for disks in the Lupus star-forming region, with an assumed interstellar CO/H2 abundance ratio. Unfortunately, observations of T-Tauri disks show that CO abundance is not interstellar, a finding reproduced by models that show CO abundance decreasing both with distance from the star and as a function of time. Here, we present radiative transfer simulations that assess the accuracy of CO-based disk mass measurements. We find that the combination of CO chemical depletion in the outer disk and optically thick emission from the inner disk leads observers to underestimate gas mass by more than an order of magnitude if they use the standard assumptions of interstellar CO/H2 ratio and optically thin emission. Furthermore, CO abundance changes on million-year timescales, introducing an age/mass degeneracy into observations. To reach a factor of a few accuracy for CO-based disk mass measurements, we suggest that observers and modelers adopt the following strategies: (1) select low-J transitions; (2) observe multiple CO isotopologues and use either intensity ratios or normalized line profiles to diagnose CO chemical depletion; and (3) use spatially resolved observations to measure the CO-abundance distribution.

Detection of exocometary CO within the 440 Myr-old Fomalhaut belt: a similar CO+CO2 ice abundance in exocomets and Solar System comets

Detection of exocometary CO within the 440 Myr-old Fomalhaut belt: a similar CO+CO2 ice abundance in exocomets and Solar System comets 

Authors:

Matrà et al

Abstract:
Recent ALMA observations present mounting evidence for the presence of exocometary gas released within Kuiper belt analogues around nearby main sequence stars. This represents a unique opportunity to study their ice reservoir at the younger ages when volatile delivery to planets is most likely to occur. We here present the detection of CO J=2-1 emission co-located with dust emission from the cometary belt in the 440 Myr-old Fomalhaut system. Through spectro-spatial filtering, we achieve a 5.4σ detection and determine that the ring's sky-projected rotation axis matches that of the star. The CO mass derived (0.65−42×10−7 M⊕) is the lowest of any circumstellar disk detected to date, and must be of exocometary origin. Using a steady state model, we estimate the CO+CO2 mass fraction of exocomets around Fomalhaut to be between 4.6-76%, consistent with Solar System comets and the two other belts known to host exocometary gas. This is the first indication of a similarity in cometary compositions across planetary systems that may be linked to their formation scenario and is consistent with direct ISM inheritance. In addition, we find tentative evidence that (49±27)% of the detected flux originates from a region near the eccentric belt's pericentre. If confirmed, the latter may be explained through a recent impact event or CO pericentre glow due to exocometary release within a steady state collisional cascade. In the latter scenario, we show how the azimuthal dependence of the CO release rate leads to asymmetries in gas observations of eccentric exocometary belts.

Different dust and gas radial extents in protoplanetary disks: consistent models of grain growth and CO emission

Different dust and gas radial extents in protoplanetary disks: consistent models of grain growth and CO emission 

Authors:

Facchini et al

Abstract:
ALMA observations of protoplanetary disks confirm earlier indications that there is a clear difference between the dust and gas radial extents. The origin of this difference is still debated, with both radial drift of the dust and optical depth effects suggested in the literature. In this work, the feedback of realistic dust particle distributions onto the gas chemistry and molecular emissivity is investigated, with a particular focus on CO isotopologues. The radial dust grain size distribution is determined using dust evolution models that include growth, fragmentation and radial drift. A new version of the code DALI is used to take into account how dust surface area and density influence the disk thermal structure, molecular abundances and excitation. The difference of dust and gas radial sizes is largely due to differences in the optical depth of CO lines and millimeter continuum, without the need to invoke radial drift. The effect of radial drift is primarily visible in the sharp outer edge of the continuum intensity profile. The gas outer radius probed by 12CO emission can easily differ by a factor of ∼2 between the models for a turbulent α ranging between typical values. Grain growth and settling concur in thermally decoupling the gas and dust components, due to the low collision rate with large grains. As a result, the gas can be much colder than the dust at intermediate heights, reducing the CO excitation and emission, especially for low turbulence values. Also, due to disk mid-plane shadowing, a second CO thermal desorption (rather than photodesorption) front can occur in the warmer outer mid-plane disk. The models are compared to ALMA observations of HD 163296 as a test case. In order to reproduce the observed CO snowline of the system, a binding energy for CO typical of ice mixtures needs to be used rather than the lower pure CO value.

Water, Carbon Monoxide & Carbon Dioxide Distributions in hot Jupiter WASP-43b's Atmosphere

Spitzer Phase Curve Constraints for WASP-43b at 3.6 and 4.5 microns

Authors:

Stevenson et al

Abstract:

Previous measurements of heat redistribution efficiency (the ability to transport energy from a planet's highly-irradiated dayside to its eternally-dark nightside) show considerable variation between exoplanets. Theoretical models predict a correlation between heat redistribution efficiency and temperature for tidally-locked planets; however, recent Hubble Space Telescope (HST) WASP-43b spectroscopic phase curve results are inconsistent with current predictions. Using the Spitzer Space Telescope, we obtained a total of three phase curve observations of WASP-43b at 3.6 and 4.5 microns. The first 3.6 micron visit exhibits spurious nightside emission that requires invoking unphysical conditions in our atmospheric retrievals. The two other visits exhibit strong day-night contrasts that are consistent with the HST data. To reconcile the departure from theoretical predictions, WASP-43b would need to have a high-altitude, nightside cloud/haze layer blocking its thermal emission. Clouds/hazes could be produced within the planet's cool, nearly-retrograde mid-latitude flows before dispersing across its nightside at high altitudes. Since mid-latitude flows only materialize in fast-rotating (≲1 day) planets, this may explain an observed trend connecting measured day-night contrast with planet rotation rate that matches all current Spitzer phase curve results. Combining independent planetary emission measurements from multiple phases, we obtain a precise dayside hemisphere H2O abundance (2.5×10−5−1.1×10−4 at 1σ confidence) and, assuming chemical equilibrium and a scaled solar abundance pattern, we derive a corresponding metallicity estimate that is consistent with being solar (0.4 -- 1.7). Using the retrieved global CO+CO2 abundance under the same assumptions, we estimate a comparable metallicity of 0.3 - 1.7× solar.

Evidence for a CO desorption front in the outer AS 209 disk

Evidence for a CO desorption front in the outer AS 209 disk

Authors:

Huang et al

Abstract:

Millimeter observations of CO isotopologues are often used to make inferences about protoplanetary disk gas density and temperature structures. The accuracy of these estimates depends on our understanding of CO freezeout and desorption from dust grains. Most models of these processes indicate that CO column density decreases monotonically with distance from the central star due to a decrease in gas density and freezeout beyond the CO snowline. We present ALMA Cycle 2 observations of 12CO, 13CO, and C18O J=2−1 emission that instead suggest CO enhancement in the outer disk of T Tauri star AS 209. Most notably, the C18O emission consists of a central peak and a ring at a radius of ∼1″ (120 AU), well outside the expected CO snowline. We propose that the ring arises from the onset of CO desorption near the edge of the millimeter dust disk. CO desorption exterior to a CO snowline may occur via non-thermal processes involving cosmic rays or high-energy photons, or via a radial thermal inversion arising from dust migration.

The Carbon monoxide Snowline is at 17-23 AU for TW Hydrae's Protoplanetary Disk

The Radial Distribution of H2 and CO in TW Hya as Revealed by Resolved ALMA Observations of CO Isotopologues

Authors:

Schwartz et al

Abstract:

CO is widely used as a tracer of molecular gas. However, there is now mounting evidence that gas phase carbon is depleted in the disk around TW Hya. Previous efforts to quantify this depletion have been hampered by uncertainties regarding the radial thermal structure in the disk. Here we present resolved ALMA observations of 13CO 3-2, C18O 3-2, 13CO 6-5, and C18O 6-5 emission in TW Hya, which allow us to derive radial gas temperature and gas surface density profiles, as well as map the CO abundance as a function of radius. These observations provide a measurement of the surface CO snowline at ~30 AU and show evidence for an outer ring of CO emission centered at 53 AU, a feature previously seen only in less abundant species. Further, the derived CO gas temperature profile constrains the freeze-out temperature of CO in the warm molecular layer to < 21 K. Combined with the previous detection of HD 1-0, these data constrain the surface density of the warm H2 gas in the inner ~30 AU. We find that CO is depleted by two orders of magnitude from R=10-60 AU, with the small amount of CO returning to the gas phase inside the surface CO snowline insufficient to explain the overall depletion. Finally, this new data is used in conjunction with previous modeling of the TW Hya disk to constrain the midplane CO snowline to 17-23 AU.

Dust Properties Across the CO Snowline in HD 163296's Protoplanetary Disk

Dust properties across the CO snowline in the HD 163296 disk from ALMA and VLA observations

Authors:

Guidi et al

Abstract:

To characterize the mechanisms of planet formation it is crucial to investigate the properties and evolution of protoplanetary disks around young stars, where the initial conditions for the growth of planets are set. Our goal is to study grain growth in the disk of the young, intermediate mass star HD163296 where dust processing has already been observed, and to look for evidence of growth by ice condensation across the CO snowline, already identified in this disk with ALMA. Under the hypothesis of optically thin emission we compare images at different wavelengths from ALMA and VLA to measure the opacity spectral index across the disk and thus the maximum grain size. We also use a Bayesian tool based on a two-layer disk model to fit the observations and constrain the dust surface density. The measurements of the opacity spectral index indicate the presence of large grains and pebbles (≥1 cm) in the inner regions of the disk (inside ∼50 AU) and smaller grains, consistent with ISM sizes, in the outer disk (beyond 150 AU). Re-analysing ALMA Band 7 Science Verification data we find (radially) unresolved excess continuum emission centered near the location of the CO snowline at ∼90 AU. Our analysis suggests a grain size distribution consistent with an enhanced production of large grains at the CO snowline and consequent transport to the inner regions. Our results combined with the excess in infrared scattered light found by Garufi et al. (2014) suggests the presence of a structure at 90~AU involving the whole vertical extent of the disk. This could be evidence for small scale processing of dust at the CO snowline.

Variability in the CO ro-vibrational lines from HD 163296

Variability in the CO ro-vibrational lines from HD163296

Authors:

Hein Bertelsen et al

Abstract:

We present for the first time a direct comparison of multi-epoch (2001-2002 and 2012) CO ro-vibrational emission lines from HD163296. We find that both the line shapes and the FWHM (Full Width Half Maximum) differ between these two epochs. The FWHM of the median observed line profiles are 10-25 km/s larger in the earlier epoch, and confirmed double peaks are only present in high J lines from 2001-2002. The line wings of individual transitions are similar in the two epochs making an additional central component in the later epoch a likely explanation for the single peaks and the lower FWHM. Variations in NIR brightness have been reported and could be linked to the observed variations. Additionally, we use the thermo chemical disc code ProDiMo to compare for the first time the line shapes, peak separations, FWHM, and line fluxes, to those observed. The ProDiMo model reproduces the peak separations, and low and mid J line fluxes well. The FWHM however, are over predicted and high J line fluxes are under predicted. We propose that a variable non-Keplerian component of the CO ro-vibrational emission, such as a disc wind or an episodic accretion funnel, is causing the difference between the two data sets collected at different epochs, and between model and observations. Additional CO ro-vibrational line detections (with CRIRES/VLT or NIRSPEC/Keck) or [Ne II] line observations with VISIR/VLT could help to clarify the cause of the variability.

First Detections of [CI] and Constraints on the Carbon Abundance

Observations and modelling of CO and [CI] in disks. First detections of [CI] and constraints on the carbon abundance

Authors:

Kama et al

Abstract:

The gas-solid budget of carbon in protoplanetary disks is related to the composition of the cores and atmospheres of the planets forming in them. The key gas-phase carbon carriers CO, C0 and C+ can now be observed in disks. The gas-phase carbon abundance in disks has not yet been well characterized, we aim to obtain new constraints on the [C]/[H] ratio in a sample of disks, and to get an overview of the strength of [CI] and warm CO emission.

We carried out a survey of the CO6--5 and [CI]1--0 and 2--1 lines towards 37 disks with APEX, and supplemented it with [CII] data from the literature. The data are interpreted using a grid of models produced with the DALI code. We also investigate how well the gas-phase carbon abundance can be determined in light of parameter uncertainties.

The CO6--5 line is detected in 13 out of 33 sources, the [CI]1--0 in 6 out of 12, and the [CI]2--1 in 1 out of 33. With deep integrations, the first unambiguous detections of [CI]~1--0 in disks are obtained, in TW~Hya and HD~100546.

Gas-phase carbon abundance reductions of a factor 5--10 or more can be identified robustly based on CO and [CI] detections. The atomic carbon detection in TW~Hya confirms a factor 100 reduction of [C]/[H]gas in that disk, while the data are consistent with an ISM-like carbon abundance for HD~100546. In addition, BP~Tau, T~Cha, HD~139614, HD~141569, and HD~100453 are either carbon-depleted or gas-poor disks. The low [CI]~2--1 detection rates in the survey mostly reflect insufficient sensitivity to detect T~Tauri disks. The Herbig~Ae/Be disks with CO and [CII] upper limits below the models are debris disk like systems. A roughly order of magnitude increase in sensitivity compared to our survey is required to obtain useful constraints on the gas-phase [C]/[H] ratio in most of the targeted systems.

There may be Multiple Carbon monoxide Snow-lines in Protoplanetary Disks

Multiple Carbon monoxide Snow-lines in Disks Sculpted by Radial Drift

Author:

Ilsedore Cleeves

Abstract:

Observations of protoplanetary disks suggest that the gas and dust follow significantly different radial distributions. This finding can be theoretically explained by a combination of radial drift and gas drag of intermediate-sized dust grains. Using a simple parametric model to approximate the different distributions of the gas and dust components, we calculate and examine the impact of radial drift on the global dust temperature structure. We find that the removal of large grains beyond the "truncation radius" allows this region to become significantly warmer from reprocessed stellar radiation shining down from the disk upper layers, increasing the outer disk temperature by ∼10−30%. This change is sufficient to raise the local temperature to a value exceeding the CO desorption temperature. These findings imply that the disk density structures induced by radial drift are able to create multiple CO snow-lines. The inner disk CO is in the gas phase, freezing out near the classical snow-line at R∼20−40 AU. Moving outward, the CO sublimates once again beyond the truncation radius (80 AU in our models) and subsequently re-freezes out at sufficiently large stellar distances, beyond R≳130−200 AU. We find that thermal desorption of CO in the outer disk becomes competitive with external UV photodesorption and that this additional transition from solid state CO to the gas-phase has significant implications for the C/O ratio in the outer disk.

Is Carbon monoxide Detection in an ExoPlanetary Atmosphere an 'Anti-biosignature?'

On the detection of carbon monoxide as an anti-biosignature in exoplanetary atmospheres

Authors:

Wang et al

Abstract:

Recent works suggest that oxygen can be maintained on lifeless exoplanets in the habitable zones of M dwarfs as the results of photochemical reactions. However, the same photochemical models also predict high concentrations of carbon monoxide (CO) in the corresponding atmospheres. Here we use a line-by-line radiative transfer model to investigate the observation requirements of O2 and CO in such atmospheres. The results show that photochemically produced CO can be readily detected at 1.58, 2.34, and 4.67 μm. We suggest that future missions aiming at characterization of exoplanetary atmospheres consider detections of CO as an anti-biosignature.

The Differences Between the Water, Carbon monoxide and Carbon dioxide Snowlines in Protoplanetary Disks

C/O and Snowline Locations in Protoplanetary Disks: The Effect of Radial Drift and Viscous Gas Accretion

Authors:

Piso et al

Abstract:

The C/O ratio is a defining feature of both gas giant atmospheric and protoplanetary disk chemistry. In disks, the C/O ratio is regulated by the presence of snowlines of major volatiles at different distances from the central star. We explore the effect of radial drift of solids and viscous gas accretion onto the central star on the snowline locations of the main C and O carriers in a protoplanetary disk, H2O, CO2 and CO, and their consequences for the C/O ratio in gas and dust throughout the disk. We determine the snowline locations for a range of fixed initial particle sizes and disk types. For our fiducial disk model, we find that grains with sizes ~0.5 cm less than s less than 7 m for an irradiated disk, and ~0.001 cm less than s less than 7 m for an evolving and viscous disk, desorb at a size-dependent location in the disk, which is independent of the particle's initial position. The snowline radius decreases for larger particles, up to sizes of ~7 m. Compared to a static disk, we find that radial drift and gas accretion in a viscous disk move the H2O snowline inwards by up to 40%, the CO2 snowline by up to 60%, and the CO snowline by up to 50%. We thus determine an inner limit on the snowline locations when radial drift and gas accretion are accounted for.

Imaging the Carbon monoxide Snowline in HD 163296's Protoplanetary Disk

Chemical Imaging of the CO Snow Line in the HD 163296 Disk

Authors:

Qi et al

Abstract:

The condensation fronts (snow lines) of H2O, CO and other abundant volatiles in the midplane of a protoplanetary disk affect several aspects of planet formation. Locating the CO snow line, where the CO gas column density is expected to drop substantially, based solely on CO emission profiles is challenging. This has prompted an exploration of chemical signatures of CO freeze-out. We present ALMA Cycle 1 observations of the N2H+ J=3-2 and DCO+ J=4-3 emission lines toward the disk around the Herbig Ae star HD~163296 at ~0.5" (60 AU) resolution, and evaluate their utility as tracers of the CO snow line location. The N2H+ emission is distributed in a ring with an inner radius at 90 AU, corresponding to a midplane temperature of 25 K. This result is consistent with a new analysis of optically thin C18O data, which implies a sharp drop in CO abundance at 90 AU. Thus N2H+ appears to be a robust tracer of the midplane CO snow line. The DCO+ emission also has a ring morphology, but neither the inner nor the outer radius coincides with the CO snow line location of 90 AU, indicative of a complex relationship between DCO+ emission and CO freeze-out in the disk midplane. Compared to TW Hya, CO freezes out at a higher temperature in the disk around HD 163296 (25 vs. 17 K in the TW Hya disk), perhaps due to different ice compositions. This highlights the importance of actually measuring the CO snow line location, rather than assuming a constant CO freeze-out temperature for all disks.

An Empirical Sequence of Disk gap Opening Revealed by Rovibrational CO

An empirical sequence of disk gap opening revealed by rovibrational CO

Authors:

Banzantti et al

Abstract:

The fundamental rovibrational band of CO near 4.7 μm is a sensitive tracer of the presence and location of molecular gas in the planet-forming region of protoplanetary disks at 0.01--10 AU. We present a new analysis of a high-resolution spectral survey (R∼96,000, or ∼3.2kms−1) of CO rovibrational lines from protoplanetary disks spanning a wide range of stellar masses and of evolutionary properties. We find that the CO emission originates in two distinct velocity components. Line widths of both components correlate strongly with disk inclination, as expected for gas in Keplerian rotation. By measuring the line flux ratios between vibrational transitions Fv=2−1/Fv=1−0, we find that the two velocity components are clearly distinct in excitation. The broad component (FWHM=50−200kms−1) probes the disk region near the magnetospheric accretion radius at ≈0.05 AU, where the gas is hot (800−1500 K). The narrow component (FWHM=10−50kms−1) probes the disk at larger radii of 0.1--10\,AU, where the gas is typically colder (200--700 K). CO excitation temperatures and orbital radii define an empirical temperature-radius relation as a power law with index −0.3±0.1 between 0.05--3 AU. The broad CO component, co-spatial with the observed orbital distribution of hot Jupiters, is rarely detected in transitional and Herbig Ae disks, providing evidence for an early dissipation of the innermost disk. An inversion in the temperature profile beyond 3 AU is interpreted as a tracer of a regime dominated by UV pumping in largely devoid inner disks, and may be a signature of the last stage before the disk enters the gas-poor debris phase.

The Weirdness of CO2, CO and H2O in Exoplanetary Atmospheres

Carbon Dioxide in Exoplanetary Atmospheres: Rarely Dominant Compared to Carbon Monoxide and Water

Authors:

Heng et al

Abstract:

We present a comprehensive study of the abundance of carbon dioxide in exoplanetary atmospheres. We construct analytical models of systems in chemical equilibrium that include carbon monoxide, carbon dioxide, water, methane and acetylene and relate the equilibrium constants of the chemical reactions to temperature and pressure via the tabulated Gibbs free energies. We prove that such chemical systems may be described by a quintic equation for the mixing ratio of methane. By examining the abundances of these molecules across a broad range of temperatures (spanning equilibrium temperatures from 600 to 2500 K), pressures (via temperature-pressure profiles that explore albedo and opacity variations) and carbon-to-oxygen ratios (from 0.1 to 100), we conclude that carbon dioxide is subdominant compared to carbon monoxide and water. Atmospheric mixing does not alter this conclusion if carbon dioxide is subdominant everywhere in the atmosphere. Carbon dioxide and carbon monoxide may attain comparable abundances if the metallicity is greatly enhanced, but this property is negated by temperatures above 1000 K. For hydrogen-dominated atmospheres, our generic result has the implication that retrieval studies need to set the subdominance of carbon dioxide as a prior of the calculation and not let its abundance completely roam free as a fitting parameter, because it directly affects the inferred value of the carbon-to-oxygen ratio and may produce unphysical conclusions. We discuss the relevance of these implications for the hot Jupiter WASP-12b and suggest that some of the previous results are chemically impossible. The relative abundance of carbon dioxide to acetylene is potentially a sensitive diagnostic of the carbon-to-oxygen ratio.

Hot Neptune GJ 436b's Methane:Carbon monoxide Ratio Explained Through Micrometeoroid Impacts

TOWARD THE FORMATION OF CARBONACEOUS REFRACTORY MATTER IN HIGH TEMPERATURE HYDROCARBON-RICH ATMOSPHERES OF EXOPLANETS UPON MICROMETEOROID IMPACT

Authors:

Dangi et al

Abstract:

We report on laboratory simulation experiments mimicking the chemical processing of model atmospheres of exoplanets containing C3 and C4 hydrocarbons at moderate temperatures of 400 K upon interaction of catalytic surfaces of micrometeoroids. By utilizing an ultrasonic levitator device and heating singly levitated particles under simulated microgravity conditions, Raman spectroscopy is utilized as a non-invasive tool to probe on line and in situ the conversion of C3 and C4 hydrocarbons to refractory carbonaceous matter on the surfaces of levitated particles. Secondary Ion Mass Spectrometry and electron microscopic imaging were also conducted to gain further insight into the elementary composition and structures of the refractories formed. Our results provide compelling evidence that in the presence of a catalytic surface, which can be supplied in the form of micrometeoroids and atmospheric dust particles, hydrocarbon gases present in the atmospheres of exoplanets can be converted to refractory, carbon-rich carbonaceous matter of mainly graphitic structure with a carbon content of at least 90% at elevated temperatures. This finding might explain the low methane to carbon monoxide (CH4–CO) ratio in the hot Neptune GJ 436b, where the abundant methane photochemically converts to higher order hydrocarbons and ultimately to refractory graphite-like carbon in the presence of a silicon surface.

Chemistry in Protoplanetary Disks

Chemistry in Protoplanetary Disks: the gas-phase CO/H2 ratio and the Carbon reservoir

Authors:

Reboussin et al

Abstract:

The gas mass of protoplanetary disks, and the gas-to-dust ratio, are two key elements driving the evolution of these disks and the formation of planetary system. We explore here to what extent CO (or its isotopologues) can be used as a tracer of gas mass. We use a detailed gas-grain chemical model and study the evolution of the disk composition, starting from a dense pre-stellar core composition. We explore a range of disk temperature profiles, cosmic rays ionization rates, and disk ages for a disk model representative of T Tauri stars. At the high densities that prevail in disks, we find that, due to fast reactions on grain surfaces, CO can be converted to less volatile forms (principally s-CO2, and to a lesser extent s-CH4) instead of being evaporated over a wide range of temperature. The canonical gas-phase abundance of 10−4 is only reached above about 30-35 K. The dominant Carbon bearing entity depends on the temperature structure and age of the disk. The chemical evolution of CO is also sensitive to the cosmic rays ionization rate. Larger gas phase CO abundances are found in younger disks. Initial conditions, such as parent cloud age and density, have a limited impact. This study reveals that CO gas-phase abundance is heavily dependent on grain surface processes, which remain very incompletely understood so far. The strong dependence on dust temperature profile makes CO a poor tracer of the gas-phase content of disks.